Numerical investigation of coupled mass transport and electrochemical reactions in porous SOFC anode microstructure

作者：Xu, Han; Dang, Zheng^*

来源：International Journal of Heat and Mass Transfer, 2017, 109: 1252-1260.

DOI：10.1016/j.ijheatmasstransfer.2017.02.090

• Solid oxide fuel cell
• Heterogeneous anode microstructure
• Electrochemical kinetics
• Coupled interaction
• Lattice Boltzmann method

To investigate the coupled mass transport and electrochemical reactions in porous anode of solid oxide fuel cell (SOFC), a pore scale model employing the multi-component Lattice Boltzmann (LB) model for mass transport in the pore phase and a six-step reaction for electrochemical reactions at three phase boundaries is established. This model is superior in including the effects of heterogeneity of anode microstructure, making it qualified to quantitatively simulate local distributions of various physical fields without dependence on any statistical parameters. The characteristics of coupled interactions of mass transport and electrochemical reaction are analyzed visually by comparing H-2 molar fraction distributions within the pore phase of the anode. It is demonstrated that, for anodes with different heterogeneous microstructures but with same porosity and tortuosity factor, the mass transport and electrochemical reaction process can be quite different, even under the same boundary conditions. Meanwhile, based on the same anode microstructure, species molar fraction varies similarly along the primary transport direction, even though the operating conditions are quite different. Besides, the influences of fuel composition, activation overpotential and operating temperature are also discussed at pore scale by the present model.

• 出版日期2017-6
• 单位西安交通大学