Dynamic pi-Conjugated Polymer Ionic Networks

作者:Shinde Shekhar; Sartucci Jenna L; Jones Dorothy K; Gavvalapalli Nagarjuna*
来源:Macromolecules, 2017, 50(19): 7577-7583.
DOI:10.1021/acs.macromol.7b01896

摘要

The elastic nature of pi-conjugated polymer gels makes it difficult to process them using traditional coating techniques and inkjet printing, and as injectable gels, thereby limiting the use of preprocessing and storing the polymers as gels. Taking cues from the easy processability of reversible and thixotropic non-pi-conjugated polymer gels, we report herein for the first time a simple strategy to obtain reversible and thixotropic pi-conjugated polymer ionic network (pi-PIN) gels. Reversible and thixotropic pi-PINT gels are generated by synergistically combining the intriguing properties of pi-conjugated polymers with the dynamic properties of ionically cross-linked networks.

  • 出版日期2017-10-10