A 3D Cd(II) Coordination Polymer With SRA Topology

作者：Zhou Ming; Xiao Zizhong; Han Zhengbo^*

来源：Synthesis and Reactivity in Inorganic Metal-Organic and Nano-Metal Chemistry, 2015, 45(5): 759-763.

DOI：10.1080/15533174.2013.841236

• coordination polymer
• Cd(II)
• crystal structure
• MOFs
• SRA topology

One new cadmium(II) coordination polymer, [Cd(pzdc)(H2O)] (1) (H(2)pzdc = pyrazine-2,3-dicarboxylic acid) has been synthesized by the reaction of Cd(II) ions with H2pzdc under the solvothermal condition and characterized by elemental analysis, IR, TG, and single-crystal X-ray diffraction. The X-ray diffraction analysis reveals that 1 (C6H4CdN2O5) crystallizes in the orthorhombic crystal system, space group Pnma. In compound 1, the pzdc ligands link Cd(II) ions into a 3D 4-connected {4(2).6(3).8}(SRA) topological net.

• 出版日期2015
• 单位辽宁大学