A novel Cd-II coordination polymer with helical units and mix-connected network topology constructed form 2-propyl-4,5-imidazoledicarboxylate and N-donor co-ligands

作者：Meng Cai Xia; Li Dong Sheng^*; Zhao Jun; Fu Feng; Zhang Xiao Ning; Tang Long; Wang Yao Yu

来源：Inorganic Chemistry Communications, 2009, 12(8): 793-795.

DOI：10.1016/j.inoche.2009.06.011

• Cd-II coordination polymer
• Helical structure
• Network topology
• Luminescent property

A novel 2D coordination polymer, formulated as [Cd-2(Hpimdc)(2)(bpp)(H2O)](n) (bpp=1,3-bis(4-pyridyl)propane, H(3)pimdc=2-propyl-4,5-imidazoledicarboxylate), has been hydro-thermally synthesized and structurally characterized, which shows unusual multifarious helical structures and (3,4)-connected network with (4.8(2))(2)(4(2).8(3).10) topology. The photoluminescent property and thermal stability of 1 were also discussed.

• 出版日期2009-8
• 单位延安大学; 西北大学; 三峡大学