Axiomatic Characterization of the Quantum Relative Entropy and Free Energy

作者：Wilming Henrik^*; Gallego Rodrigo^*; Eisert Jens^*

来源：Entropy, 2017, 19(6): 241.

DOI：10.3390/e19060241

• quantum relative entropy
• non-equilibrium free energy
• quantum thermodynamics
• correlations

Building upon work by Matsumoto, we show that the quantum relative entropy with full-rank second argument is determined by four simple axioms: (i) Continuity in the first argument; (ii) the validity of the data-processing inequality; (iii) additivity under tensor products; and (iv) super-additivity. This observation has immediate implications for quantum thermodynamics, which we discuss. Specifically, we demonstrate that, under reasonable restrictions, the free energy is singled out as a measure of athermality. In particular, we consider an extended class of Gibbs-preserving maps as free operations in a resource-theoretic framework, in which a catalyst is allowed to build up correlations with the system at hand. The free energy is the only extensive and continuous function that is monotonic under such free operations.

• 出版日期2017-6