Engineering entanglement: controlling the formation of polycatenanes and polyrotaxanes using pi interactions

作者:Boer Stephanie A; Hawes Chris S; Turner David R*
来源:Chemical communications, 2014, 50(9): 1125-1127.
DOI:10.1039/c3cc48802k

摘要

A reproducible metallocyclic motif containing amino-acid functionalised aromatic diimides has been employed to demonstrate remarkable control over entanglement topologies. [2] -Catenane and pseudo-rotaxane units give rise to 1D -> 2D polycatenation, the formation of which can be sterically prevented, and a unique 1D -> 3D polyrotaxane.

  • 出版日期2014