A highly stable and luminescent mononuclear Cu(I) bis-{5-tert-butyl-3-(6-methyl-2-pyridyl)-1H-1,2,4-triazole} complex

作者：Luo, Yan-Sheng; Chen, Jing-Lin^*; Zeng, Xue-Hua; Qiu, Lu; He, Li-Hua; Liu, Sui-Jun; Wen, He-Rui

来源：Chinese Chemical Letters, 2017, 28(5): 1027-1030.

DOI：10.1016/j.cclet.2016.12.015

• Cu(I) complex
• 1,2,4-Triazole
• 6-Methyl-2-pyridyl
• Luminescence
• Crystal structure

A new emissive mononuclear homoleptic Cu(I) complex of 5-tert-butyl-346-methy1-2-pyridyl)-1H1,2,4-triazole (bmptzH), [Cu(bmptzH)2](CIO4) (1), has been synthesized by treatment of [Cu (PPh3)(2)(CH3CN)(2)](CIO4) or [Cu(CH3CN)(4)](CIO4) with the bmptzH ligand. It is revealed that complex 1 displays a distorted N-4 tetrahedral arrangement formed by two bmptzH chelates, in which bmptzH adopts a neutral bidentate chelating coordination mode using the N atom of the pyridyl ring and the 4-N not 2-N atom of the 1,2,4-triazolyl ring. It is shown that complex 1 is highly stable and exhibits good luminescence properties in solution and solid states at room temperature due to the introduction of a methyl group at the ortho-position of the pyridyl ring.

• 出版日期2017-5
• 单位江西理工大学