Aquabis(benzoato-kappa O)(5,5 '-dimethyl-2,2 '-bipyridine-kappa N-2,N ')copper(II)

作者：Dong Xi Yan^*; Xu Xiaojie; Yang Lei

来源：Acta Crystallographica Section E-Structure Reports Online, 2009, 65(11): M1290-U457.

DOI：10.1107/S1600536809039191

In the crystal structure of the title compound, [Cu(C7H5O2)(2)-(C12H12N2)(H2O)], the Cu II ion is pentacoordinated in a distorted square-pyramidal geometry by two O atoms of two benzoate anions and two N atoms of a 5,5'-dimethyl-2,2'-bipyridine ligand occupying the basal plane, and a water O atom located at the apical site. In the crystal structure, O-H center dot center dot center dot O hydrogen bonds link the molecules into a supra-molecular structure. The crystal studied was a racemic twin, as suggested by the Flack parameter of 0.584 (14).

• 出版日期2009-11
• 单位河南理工大学