mu-Oxalato-kappa O-4(1),O-2 : O-1 ',O-2 '-bis{[N,N '-bis(pyridin-2-ylmethylene)propane-1,2-diamine-kappa(4)-N,N ',N '',N ''']copper(II)} bis(perchlorate)

作者：Liu Tian Fu^*

来源：Acta Crystallographica Section E-Structure Reports Online, 2007, 63: M1856-M1858.

DOI：10.1107/S1600536807022659

In the centrosymmetric dinuclear title complex, [ Cu-2( C2O4)( C15H16N4) (2)]( ClO4) (2), each Cu (II) ion is in an elongated octahedral environment, coordinated by two oxalate O atoms and four N atoms from the tetradentate ligand. One O atom and three N atoms are in the equatorial plane, and another O atom and one N atom are in axial sites. Each copper ion is bound to two O atoms from the two different carboxylate groups of the oxalate ligands, with a Cu center dot center dot center dot Cu distance of 5.6623 ( 16) angstrom. The anions lie on twofold rotation axes.

• 出版日期2007-7
• 单位北京理工大学