A 3D Porous Coordination Polymer from Tetrazole Ligand and Cd(II): Crystal Structure, Luminescent Property and Adsorption of Methanol and Water

作者：Li Bo; Yu Kai^*; Wang Chunmei; Su Zhanhua; Wang Chunxiao; Zhou Baibin

来源：Journal of Inorganic and Organometallic Polymers and Materials, 2014, 24(3): 525-530.

DOI：10.1007/s10904-013-0015-7

• Coordination polymer
• Tetrazole ligand
• Cadmium complexes
• Gas adsorption
• Luminescent property

An unusual tetrazole-based Cd(II) coordination polymer, [Cd(4-tzba)(H2O)](n) (tzba = 4-(tetrazolyl)benzenecarboxylic acid) (1), was synthesized by hydrothermal reaction and structurally characterized by single-crystal X-ray diffraction. The structure of 1 contains distorted octahedral cadmium centers coordinated by four different tzba(2-) ligands and a water molecule. All the tzba(2-) ligands display coordination of type, mu 4-kappa N1:kappa N3:kappa N4:kappa O1, O2, which connects four Cd(II) atoms to form an intricate 3-D network. There are three kinds of apertures in the structure of 1; two helical channels and a hexagonal aperture are observed along different axes. Polymer 1 exhibits selective gas adsorption behavior for methanol, ethanol and water. In addition, 1 shows blue photoluminescence mainly arising from intraligand transitions of the aromatic rings in the tbza(2-) ligand.

• 出版日期2014-5
• 单位哈尔滨师范大学; 黑河学院; 黑龙江大学