A novel inorganic and organic mixture cations templated indium phosphate: Synthesis and crystal structure

作者：Li, Ping; Liu, Zhi-Hong^*

来源：Inorganica Chimica Acta, 2011, 378(1): 323-325.

DOI：10.1016/j.ica.2011.08.067

• Indium phosphate
• Synthesis
• Hydrothermal reaction
• Crystal structure

A novel mixture cations templated indium phosphates, Li(C(2)N(2)H(10))[In(2)(HPO(4))(3)(PO(4))], has been synthesized under mild hydrothermal conditions and characterized by elemental analysis and FT-IR spectrum. The crystal structure of title compound was determined by single crystal X-ray diffraction data. It belongs to monoclinic, space group P2/n with unit cell dimension a = 9.4692(13) angstrom, b = 9.1622(12) angstrom, c = 9.7063 (14) angstrom, beta = 117.5620(10)degrees. Its structure is characterized as a three-dimensional open-framework with 8-membered ring channels along a axis, where the inorganic lithium cation and organic double-protonated ethylenediamine cation are located and interact with the framework both electrostatically and via hydrogen bonds of N-H center dot center dot center dot O.

• 出版日期2011-11-30
• 单位陕西师范大学