Cooperative Catalysis: Electron-Rich Fe-H Complexes and DMAP, a Successful %26quot;Joint Venture%26quot; for Ultrafast Hydrogen Production

作者：Rommel Susanne; Hettmanczyk Lara; Klein Johannes E M N; Plietker Bernd^*

来源：Chemistry-An Asian Journal, 2014, 9(8): 2140-2147.

DOI：10.1002/asia.201402142

• catalysis
• hydrogen
• iron
• organometallic complexes
• silylation

A series of defined iron-hydrogen complexes was prepared in a straightforward one-pot approach. The structure and electronic properties of such complexes were investigated by means of quantum-chemical analysis. These new complexes were then applied in the dehydrogenative silylation of methanol. The complex (dppp)(CO)(NO)FeH showed a remarkable activity with a TOF of more than 600 000 h(-1) of pure hydrogen gas within seconds.

• 出版日期2014-8