An unprecedented zero field neodymium(III) single-ion magnet based on a phosphonic diamide

作者:Gupta Sandeep K; Rajeshkumar Thayalan; Rajaraman Gopalan; Murugavel Ramaswamy
来源:Chemical Communications, 2016, 52(44): 7168-7171.
DOI:10.1039/c6cc03066a

摘要

A pseudo-D5h symmetric Nd(iii)-complex exhibits zero-field SIM behavior as a result of a strong axial crystal field, stabilization of the rare mJ = |±9/2〉 ground state, and small transverse anisotropy.

  • 出版日期2016
  • 单位Indian Institute of Technology