Novel redox-active polycarbazole-functionalized polycatechol network films produced by controlled electropolymerization

作者：Huang, Yao; Lu, Baoyang; Xu, Jingkun^*; Zhu, Guang; Chen, Shuai; Yue, Ruirui

来源：Journal of Applied Polymer Science, 2012, 126(5): 1613-1622.

DOI：10.1002/app.36670

• electrochemistry
• films
• fluorescence
• FT-IR
• MALDI

A novel precursor, 1,2-bis[6-(9H-carbazol-9-yl)hexyloxy] benzene (BCHB), was successfully synthesized. Its polycarbazole-functionalized polycatechol network films, poly{1,2-bis[6-(9H-carbazol-9-yl)hexyloxy] benzene} (PBCHB), with good redox activity were formed by the direct anodic oxidation of BCHB in CH2Cl2 and boron trifluoride diethyl etherate binary solvent solution. Ultravioletvisible spectroscopy, Fourier transform infrared spectroscopy, 1H-NMR, and matrix-assisted laser desorption ionizationtime of flight mass spectrometry were used to characterize the polymers. The results indicate that the network polymers could be synthesized electrochemically with different polymerized units by controlled electropolymerization. The PBCHB films prepared at low potential were oligomers with short conjugation lengths and were soluble in common organic solvents, whereas the polymers with long conjugation lengths and hyperbranched network structures obtained at high potential were insoluble. The electrosynthesized polymers exhibited blue emission maxima around 450 nm and were much more redshifted than their monomer. The emissions were also brighter; this indicated the polymers are potential good blue-light emitters.

• 出版日期2012-12-5
• 单位江西科技师范大学