科研之友
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摘要
The coordination polymer, [Cu2(bpp)4Cl2]Cl2, was prepared by self-assembly of benzo[f] [1,10]phenanthroline-6,7-dicarboxylic acid and bpp [bpp = 1,3-bis(4-pyridyl)propane] with CuCl22H2O, and determined by X-ray crystallographic diffraction, IR spectrum, and thermal analysis. The complex features a 3-D 4-fold interpenetrated metal-organic framework with diamondoid topology. There are two sets of diamondoid frameworks independently constructed by bpp bridging the same copper centers, and the two sets of diamondoid frameworks interpenetrate one another to form an interesting 4-fold interpenetrating 3-D architecture.
