Hydrothermal Synthesis, Crystal Structure and-Photoluminescence of a New Two-Dimensional Cadmium(II) Complex [Cd-3(HBTA)(2)(BIPA)(3)](n)

作者：Liu Guang Xiang^*; Xu Yu Yong; Ren Xiao Ming

来源：Chinese Journal of Inorganic Chemistry, 2010, 26(10): 1885-1889.

• cadmium(II) complex
• crystal structure
• multicarboxylate ligand
• luminescence

The hydrothermal reactions of 5-bromoisophthalic acid (H(2)BIPA), benzotriazole (HBTA) with Cd(NO3)(2)center dot 4H(2)O in basified solvent gave rise to a coordination polymer [Cd-3(HBTA)(2)(BIPA)(3)](n) (1), which has been characterized by elemental analysis, IR and single-crystal X-ray diffraction. Complex 1 presents a two-dimensional (2D) layer network containing the edge-sharing ID -O-Cd-O chains through repetitions of the alternating arrangement of the Cd-3(CO2)(6) cluster and displays strong luminescent emission at room temperature. CCDC: 775284.

• 出版日期2010-10-10
• 单位安庆师范大学