Antimony Doping in Solution-processed Cu2ZnSn(S,Se)(4) Solar Cells

作者：Tai Kong Fai^*; Fu Dongchuan; Chiam Sing Yang; Huan Cheng Hon Alfred; Batabyal Sudip Kumar; Wong Lydia Helena

来源：Chemsuschem, 2015, 8(20): 3504-3511.

DOI：10.1002/cssc.201500433

• antimony doping
• kesterite
• solar cells
• solution processing
• spectroscopy

Kesterite Cu2ZnSn(S,Se)(4) (CZTSSe) is obtained using a facile precursor-solution method followed by selenization. Power-conversion efficiency of 6.0% is achieved and further improved to 8.2% after doping the absorber with 0.5mol% Sb. XRD and Raman spectroscopy show similar characteristics for the undoped and doped CZTSSe. Increasing the Sb concentration increases the grain size and lowers the series resistance. However, further Sb doping beyond 0.5mol% degrades device performance due to lower open-circuit voltage (and therefore lower fill factor). The effect of Sb doping and the doping concentration are investigated by power-dependent and temperature-dependent photoluminescence studies, revealing that trap density is significant reduced with 0.5mol% Sb doping. Additional doping beyond 0.5mol% creates more defects that quench the photoexcited carriers and decrease the open-circuit voltage.

• 出版日期2015-10
• 单位南阳理工学院