A porous Sm(III) coordination nanotube with hydrophobic and hydrophilic channels

作者：Lopez Nazario; Zhao Hanhua; Zhao Dan; Zhou Hong Cai; Riebenspies Joseph P; Dunbar Kim R^*

来源：Dalton Transactions, 2013, 42(1): 54-57.

DOI：10.1039/c2dt31842c

The pi-pi stacking interactions between tptz units from adjacent Sm(tptz)(HCOO)(3) coordination nanotubes leads to additional 1D channels (tptz = 2,4,6-tris(2-pyridyl)-s-triazine). The present compound is a rare case of a tubular porous material with both hydrophobic and hydrophilic channels. Permanent porosity was confirmed by N-2 adsorption isotherms.

• 出版日期2013