A ferroelectric olefin-copper(I) organometallic polymer with flexible organic ligand (R)-MbVBP

作者：Wang, Guo-Xi^*; Xing, Zheng; Chen, Li-Zhuang; Han, Guang-Fan

来源：Journal of Molecular Structure, 2015, 1091: 16-19.

DOI：10.1016/j.molstruc.2015.02.043

• Hydrothermal synthesis
• Olefin-Cu(I) compound
• Coordination polymer
• Ferroelectricity
• Solid state structure

Hydrothermal treatment of (R)-2-methyl-1,4-bis(4-vinylbenzyl)piperazine [(R)-MbVBP] and CuCl afforded a novel olefincopper(I) coordination compound. Introducing the flexible ligand (R)-MbVBP allowed the olefincopper(I) organometallic compound to crystallize in a polar point group P2(1). The compound was ferroelectric, and its electric hysteresis loop showed a remnant polarization (Pr) of 0.130.32 mu C cm(-2) and a coercive field (Ec) of 3.5-11 kV cm(-1).

• 出版日期2015-7-5
• 单位江苏科技大学