A novel 1-D coordination polymer constructed from disilver-1,3,4-oxadiazole nodes and perchlorato bridges

作者：Anghel Catalin; Matache Mihaela^*; Paraschivescu Codruta C; Madalan Augustin M; Andruh Marius^*

来源：Inorganic Chemistry Communications, 2017, 76: 22-25.

DOI：10.1016/j.inoche.2016.12.007

• Silver coordination polymer
• 2,5-Disubstituted-1,3,4-oxadiazole
• Perchlorato bridges
• Blue luminescence

The reaction of silver perchlorate with 2-phenyl-5-(p-tolyI)-1,3,4-oxadiazole (L) affords a 1-D coordination polymer, [Ag3L4(C104)3] (1). Two silver ions are bridged by two L ligands, through the nitrogen atoms of the oxadiazole ring, resulting in binuclear units. The coordination polymer is constructed from binuclear nodes, (Ag2L2), connected by perchlorato bridges. The investigation of the optical properties of compound 1 indicates a slight change in the emission profile compared to the organic ligand, showing blue luminescence upon excitation at X = 300 nm.

• 出版日期2017-2