A hexameric [(Mn18Na6)-Na-III] wheel based on [(Mn3O)-O-III](7+) sub-units

作者:Manoli Maria; Inglis Ross; Piligkos Stergios; Yanhua Lan; Wernsdorfer Wolfgang; Brechin Euan K*; Tasiopoulos Anastasios J*
来源:Chemical Communications, 2016, 52(87): 12829-12832.
DOI:10.1039/c6cc06644e

摘要

A novel hexameric [(Mn18Na6)-Na-III] wheel-like aggregate consisting of [(Mn3O)-O-III] triangles is reported. It is the second highest nuclearity oxime-based Mn cluster, the largest member of the recently-developed family of molecular oligomers based on [(Mn3O)-O-III] triangles, and the only one with a wheel-like metal topology.

  • 出版日期2016