Aza-substitution, benzo-annulation effects and catalytic activity of beta-octaphenyl-substituted tetrapyrrolic macroheterocyclic cobalt complexes. I. heterogeneous catalysis

作者：Vashurin Artur^*; Maizlish Vladimir; Kuzmin Ilya; Petrov Oleg; Razumov Mikhail; Pukhovskaya Svetlana; Golubchikov Oleg; Koifman Oscar

来源：Journal of Inclusion Phenomena and Macrocyclic Chemistry, 2017, 87(1-2): 37-43.

DOI：10.1007/s10847-016-0674-4

• beta-Octaphenylporphyrin
• Metal complex
• Benzo-annulation
• Aza-substitution
• Sodium N,N-carbomodithiolate
• Oxidation
• Catalyst

The influence of the size of conjugated pi-system on catalytic activity of cobalt complex with beta-octaphenylporphyrin and its tetraaza-, tetrabenzo and tetrabenzotetraaza derivatives was studied in present work. It is found that catalytic activity for oxidation of sulfur-containing compounds increases under extension of conjugated macrocycle system according to the following series CoP < CoBP a CoPz < CoPPz a feminine ordinal indicator CoPc.

• 出版日期2017-2