A new hybrid porphyrin-heteropolyacid material: Synthesis, characterization and investigation as catalyst in Baeyer-Villiger oxidation. Synergistic effect

作者：Pamin K; Pronczuk M; Basag S; Kubiak W; Sojka Z; Poltowicz J^*

来源：Inorganic Chemistry Communications, 2015, 59: 13-16.

DOI：10.1016/j.inoche.2015.06.005

• Organic-inorganic hybrid
• Poyoxometalate
• Porphyrin
• Cyclohexanone oxidation

A new tetraphenylporphyrin-tungstophosphoric acid hybrid was synthesized and physico-chemically characterized by different techniques. This hybrid, its molybdenum analogue, tungstophosphoric and molybdophosphoric acids as well as their, Mn, Fe and Co salts were applied in Baeyer-Villiger oxidation of cyclohexanone to caprolactone with molecular oxygen. Due to the synergistic effect porphyrin-heteropolyacid hybrids exhibit similar catalytic activity as appropriate heteropoly salts and much higher activity than parent heteropolyacids.

• 出版日期2015-9