A further step towards tuning the properties of metal-chalcogenide nanocapsules by replacing skeletal oxide by sulphide ligands

作者：Schaeffer Christian; Todea Ana Maria; Boegge Hartmut; Floquet Sebastien; Cadot Emmanuel; Korenev Vladimir S; Fedin Vladimir P; Gouzerh Pierre; Mueller Achim

来源：Dalton Transactions, 2013, 42(2): 330-333.

DOI：10.1039/c2dt32247a

Addition of [(Mo2O2)-O-V(mu-O)(mu-S)(aq)](2+) linker-type units to a solution/ dynamic library containing tungstates results via the formation of the complementary pentagonal {(W)W-5} units logically in the self-assembly of a mixed oxide/sulphide {(W72Mo60V)-Mo-VI}-type Keplerate, thereby demonstrating the ability to tune the capsule%26apos;s skeletal softness (the (mu-O)(2) and (mu-S)(2) scenarios are known) and providing options to influence differently important capsule-substrate interactions.

• 出版日期2013