A new three-dimensional 4,8-connected inorganic open framework based on manganese phosphomolybdate with (4(12)6(12)8(4)) (4(6))(2) topology

作者：Zhang, Yu-Nan; Zhou, Bai-Bin^*; Sha, Qing-Quan; Su, Zhan-Hua; Liu, Hong

来源：Inorganic Chemistry Communications, 2010, 13(4): 550-553.

DOI：10.1016/j.inoche.2010.02.002

• Hydrothermal synthesis
• Manganese phosphomolybdate
• Inorganic open framework
• Magnetic character

A new inorganic open framework based on manganese phosphomolybdate, (C2N2H10)(4){Mn-3[P4Mo6O26-(OH)(5)](2)}center dot 6H(2)O (1), has been hydrothermally synthesized and structurally characterized by single-crystal X-ray diffraction, IR spectroscopy and TG analysis. Single-crystal X-ray diffraction analysis reveals that compound 1 exhibits a 4,8-connected three-dimensional inorganic open framework with (4(12)6(12)8(4)) (4(6))(2) topology and possesses three-dimensional channels filled by the protonated H(2)en ligands and water molecules. Additionally, DC susceptibility measurement shows the antiferromagnetic character of the exchange interactions in compound 1.

• 出版日期2010-4
• 单位哈尔滨师范大学; 哈尔滨工业大学; 黑龙江大学; 佳木斯大学