Hydrothermal synthesis, crystal structure and luminescent properties of 2d grid-like polymer based on 3d-4d mixed metals

作者：Zhao B; Yi L; Cheng P^*; Liao DZ; Yan SP; Jiang ZH

来源：Inorganic Chemistry Communications, 2004, 7(8): 971-973.

DOI：10.1016/j.inoche.2004.06.018

• hydrothermal synthesis
• coordination polymer
• 3d-4d heterometallic
• crystal structure

The hydrothermal synthesis Of V2O5, Ag2O and H2L (H2L = pyridine-2,6-dicarboxylic acid) in water at 180 degreesC for 72 It yields a novel 2D coordination polymer [VAgLO2](n) (1). Each V center chelates to a tridentate ligand L, while the tetrahedral conformation of Ag center consists of four O atoms. V and Ag polyhedra alternate by either carboxyl or oxo bridges to further form a unique 3d-4d heterometal-based 2D grid motif.

• 出版日期2004-8
• 单位南开大学