An iodine-containing metal-organic framework: Synthesis, structure and luminescent properties

作者：Guo, Jiao; He, Yuan-Chun^*; Yang, Yan; Kan, Wei-Qiu^*; Zhao, Fang-Hua; Wang, Lingyan

来源：Inorganic Chemistry Communications, 2018, 89: 64-67.

DOI：10.1016/j.inoche.2018.01.010

• Metal-organic framework
• Crystal structure
• Cd(II)
• Iodine
• Luminescent

Presented here is a three-dimensional structure [Cd-3(IN)(5)]center dot I-3(-) (1) based on isonicotinic acid. Compound 1 has been characterized by single crystal X-ray diffraction, powder crystal X-ray diffraction, infrared spectrum, thermogravimetric analysis, element analysis and scanning electron microscopy. The structure of compound 1 shows a 3D framework constructed by rod-shaped metal chains together with IN anions, while the channels are occupied by triiodide ions. The luminescent properties of 1 have also been investigated.

• 出版日期2018-3
• 单位淮阴师范学院; 新乡学院; 西安工业大学; 曲阜师范大学