Nano TiO2/SO42- as a heterogeneous solid acid catalyst for the synthesis of 5-substited-1H-tetrazoles

作者：Hosseini Sarvari Mona^*; Najafvand Derikvandi Sepideh

来源：Comptes Rendus Chimie, 2014, 17(10): 1007-1012.

DOI：10.1016/j.crci.2013.11.002

• Nano sulfated-titania
• 5-substituted-1H-tetrazoles
• [3+2] cycloaddition
• Heterogeneous catalyst

An efficient and economical protocol for the synthesis of 5-substituted-1H-tetrazoles from various nitriles and sodium azide is reported using nano TiO2/SO42- as an effective heterogeneous catalyst. A wide variety of aryl nitriles underwent [3 + 2] cycloaddition to afford tetrazoles in good to excellent yields.

• 出版日期2014-10