A new supramolecular net constructed with 2D (4,4) layer subunits displaying unique 4-connected msw/P42/nnm topology: Structure, fluorescence and catalytic properties

作者：Qin, Li; Zheng, Jing; Xiao, Shu-Lin; Zheng, Xiao-Hua; Cui, Guang-Hua^*

来源：Inorganic Chemistry Communications, 2013, 34: 71-74.

DOI：10.1016/j.inoche.2013.05.011

• Bis(benzimidazolyl)butane
• Hydrogen bonds
• Degradation
• Supramolecular framework

A new three-dimensional supramolecular framework based on 1,4-bis(5,6-dimethylbenzimidazole)butane (L) with 5-hydroxyisophthalic add (H(2)hip) has been synthesized by hydrothermal reaction, namely, [Co(L)(0.5)(hip)](n), exhibiting an unprecedented topology architecture through hydrogen bonds, viz. supramolecular net 4-connected uninodal 3D net with (6(5).8) msw/P42/nnm topology. The fluorescence and remarkable catalytic performances of the complex for the degradation of methyl orange by sodium persulfate have been investigated.

• 出版日期2013-8
• 单位华北理工大学