Nonenzymatic electrochemical detection of rutin on Pt nanoparticles/graphene nanocomposite modified glassy carbon electrode

作者：Li, Shumin; Yang, Beibei; Wang, Jin; Bin, Duan; Wang, Caiqin; Zhang, Ke; Du, Yukou^*

来源：Analytical Methods, 2016, 8(27): 5435-5440.

DOI：10.1039/c6ay01348a

• REDUCED GRAPHENE OXIDE
• IONIC LIQUID ELECTRODE
• PASTE ELECTRODE
• VOLTAMMETRIC DETECTION
• NANOMOLAR DETECTION
• GOLD NANOPARTICLES
• ASCORBIC-ACID
• URIC-ACID
• SENSOR
• NANOTUBES

In this article, a nonenzymatic electrochemical sensor based on chemically reduced graphene oxide (RGO) and a Pt nanoparticles (PtNPs) modified glassy carbon electrode has been fabricated and used to determine rutin. The nanocomposites of PtNPs/RGO were characterized by transmission electron microscopy and Xray diffraction, and the electrochemical behaviors of rutin on PtNPs/RGO were demonstrated by cyclic voltammetry and differential pulse voltammetry. The as-fabricated electrochemical sensor for rutin exhibited a wide linear range from 0.057 to 102.59 mu M with a detection limit of 0.02 mu M (S/N = 3). Additionally, the as-prepared electrode displayed a good reproducibility, stability and anti-interference ability for the detection of rutin. Finally, the electrode was successfully applied for the determination of rutin in pharmaceutical tablets.

• 出版日期2016
• 单位苏州大学