Development of Composites Based on Recycled Polyethylene/Sugarcane Bagasse Fibers

作者：Vieira de Carvalho Neto Alberto Gomes; Ganzerli Thiago Amaral; Cardozo Adriano Luciano; Favaro Silvia Luciana; Basso Pereira Antonio Guilherme; Girotto Emerson Marcelo; Radovanovic Eduardo^*

来源：Polymer Composites, 2014, 35(4): 768-774.

DOI：10.1002/pc.22720

In this work, sugarcane bagasse fibers were used as filler in composites having recycled high-density polyethylene (PEr) as matrix. Because of the poor interaction between fibers surface and the PEr, the surface of bagasse was chemically modified. This modification consists of washing with water at 80 degrees C, a mercerization process using sodium hydroxide and acetylation reaction with acetic anhydride. The chemical modification was characterized by Fourier transform infrared-horizontal attenuated total reflectance (FTIR-HATR) and C-13 nuclear magnetic resonance spectroscopies (NMR), thermogravimetric analysis (TGA), and scanning electronic microscopy (SEM). The composites were prepared from modified and unmodified fibers into PEr matrix, containing 5, 10, and 20% (w/w) of fiber. The samples were processed by extrusion and molds were prepared by injection process in order to perform mechanical tests. These materials were analyzed by SEM, TGA, and the water uptake was evaluated. Also, their mechanical properties were analyzed. Morphological analysis indicated that the chemical modification of sugarcane bagasse increased the compatibility between matrix and reinforcement. Tensile, flexural, and impact tests showed that the mechanical properties of the composite were improved compared to PEr due to the presence of the fibers. POLYM. COMPOS., 35:768-774, 2014.

• 出版日期2014-4