Hydrothermal Syntheses and Crystal Structures of Three Lanthanide(III) Complexes Based on Carboxyl Derivatives of 1,10-Phenanthroline

作者：Qiao Yu; Wei Bing; Li Xiu-Ying; Che Guang-Bo^*; Liu Chun-Bo^*; Zhang Xing-Jing; Zhu En-Wei; Liu Feng

来源：Chinese Journal of Structural Chemistry, 2017, 36(1): 73-81.

DOI：10.14102/j.cnki.0254-5861.2011-1259

• lanthanide(III) complex
• 2-(4-carboxyphenyl)imidazo(4,5-f)(1,10)phenanthroline
• benzene-1,4-dicarboxylic acid
• crystal structure
• luminescence

Three lanthanide(III) complexes [Ln(4-NCP)(1,4-BDC)]n center dot xnH(2)O (Ln = Pr (1), Sm(2), Nd (3). 4-HNCP = 2-(4-carboxyphenyl)imidazo(4,5-f)(1,10) phenanthroline, 1,4-H2BDC = benzene-1,4-dicarboxylic acid) have been hydrothermally synthesized and characterized via elemental analysis, infrared spectrometry and single-crystal X-ray diffraction. Structural analyses revealed that complexes 1 similar to 3 possess similar porous three-dimensional frameworks with the point symbol {4(12).(63)}. Meanwhile, complexes 1 similar to 3 exhibit excellent thermal stabilities and complex 2 exhibits characteristic luminescent property.

• 出版日期2017-1-16
• 单位江苏大学; 吉林师范大学