Novel Tin(IV) Complexes with the Hybrid Guanidine Ligand DMEGqu

作者：Jesser Anton; Vieira Ines dos Santos; Herres Pawlis Sonja^*

来源：Zeitschrift fur Naturforschung Section B-A Journal of Chemical Sciences, 2013, 68(5-6): 653-665.

DOI：10.5560/ZNB.2013-3080

• Guanidine Ligands
• Tin Complexes
• X-Ray Diffraction
• Density Functional Theory

Novel Sn(IV) complexes with the guanidine-quinoline hybrid ligand DMEGqu are reported. With SnCL4, SnBr4, Me2SnCl2, Me2SnBr2, and the 3,5-di-tert-butyl-catecholate coligand complexes with different donor sets were synthesized. Four of these tin compounds have been modelled by density functional theory. Additionally, a tetranuclear Sn(IV) oxocluster with a novel structure motif, a distorted hetero-adamantane with bridging oxido and hydroxido ligands, is presented.

• 出版日期2013-6