Directly Linked Corrole Oligomers via Facile Oxidative 3-3 ' Coupling Reaction

作者：Hirabayashi Sho; Omote Masato; Aratani Naoki^*; Osuka Atsuhiro

来源：Bulletin of the Chemical Society of Japan, 2012, 85(5): 558-562.

DOI：10.1246/bcsj.20110373

Upon heating with p-chloranil in CHCl3, 5,10,15-tris(pentafluorophenyl)corrole (1H) underwent regioselective oxidative coupling reaction at the 3,3'-position to give dimer 2H and trimer 3H. Oxidation of 2H with p-fluoranil gave tetramer 4H and hexamer 6H. The crystal structures have been revealed for 2H, cobalt(111) complexed trimer 3Co center dot py(6), and tetramer 4Co center dot py(8).

• 出版日期2012-5-15