Decoration of Ceramic Foams by Ceramic Nanowires via Catalyst-Assisted Pyrolysis of Preceramic Polymers

作者:Fukushima Manabu*; Yoshizawa Yu ichi; Colombo Paolo
来源:Journal of the American Ceramic Society, 2012, 95(10): 3071-3077.
DOI:10.1111/j.1551-2916.2012.05341.x

摘要

Silicon oxynitride ( Si 2 N 2 O ) nanowires (NWs) were grown in situ on the cell walls of silicon carbide and alumina foams by coating preceramic polymers containing a Co-based catalyst, followed by pyrolysis in nitrogen at temperatures ranging from 1250 degrees C to 1450 degrees C. The relationship between different processing factors (type of substrate and preceramic polymer, pyrolysis temperature) and the growth of NWs was examined. Varying processing factors were found to be effective for controlling the growth of NWs. The use of a preceramic polymer containing a high amount of carbon as well as silica impurities present in the SiC foams led to a larger amount of longer NWs, homogeneously covering the ceramic struts of the porous substrates. The overall morphology and growing mechanism of the NWs on ceramic foams were investigated.

  • 出版日期2012-10