科研之友
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摘要
Two types of bis(imidazole) ligands-1,4-bis(imidazol-1-ylmethyl) benzene (bix) and 1,4-bis( imidazolyl)-2-butyne (bib) - have been used to bridge octahedral metal centres and form simple cubic networks. Crystal structures of Cd(bix)(3) (ClO4)(2), Cd( bix)(3) (NO3)(2), Zn(bib)(3) (BF4)(2) and Co(bib)(3) (NO3)(2) reveal that all possess the alpha-polonium topology and are triply interpenetrating.
- 出版日期2002-7-31
