Non-classical hydrogen bonding in [K(1-aza-18-crown-6)]BH4 and its 18-crown-6 counterpart

作者:Wolstenholme David J*; Sirsch Peter; Onut Lenuta; Flogeras Jenna; Decken Andreas; McGrady G Sean
来源:Dalton Transactions, 2011, 40(33): 8301-8303.
DOI:10.1039/c1dt10888c

摘要

The extended structures of [K(1-aza-18-crown-6)]BH4 and its 18-crown-6 analogue exhibits significantly different primary and secondary stabilizing interactions. However, their respective ion pairs display similar cation-to-anion interactions, in spite of the differences in the nature of the crown ether ligand.

  • 出版日期2011