A metal-mediated boron-centred isomerisation reaction via C-H activation

作者:Braunschweig Holger*; Jimenez Halla J Oscar C; Radacki Krzysztof; Shang Rong
来源:Chemical communications, 2015, 51(92): 16569-16572.
DOI:10.1039/c5cc07681a

摘要

A heterocyclic manganese complex (4) derived from a carbonyl-borylene coupling reaction undergoes isomerisation, during which the former borylene moiety migrates to the cyclopentadienyl ligand and inserts into a C-H bond. This reaction and a computational study of its mechanism are discussed.

  • 出版日期2015