科研之友
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摘要
Based on the electronic properties of different hybridized oxygen atoms (sp(3)versus sp(2)) in the structure of O,O-acetals containing an enol ether moiety, the chemoselective formation of oxocarbenium ions was realized to furnish diversified chiral heterocyclic compounds with excellent stereoselectivities by reacting with different types of nucleophiles. Additionally, an unexpected intramolecular oxocarbenium ion transfer was also reported to form polycyclic products containing the O,O-acetal functional group.
- 出版日期2018-9-21
- 单位中国海洋大学
