科研之友
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摘要
A systematic study on the effects of Lewis or BrOnsted acid co-catalysts in gold-catalyzed reactions was undertaken using representative reactions (O-, N-, and C-nucleophilic additions to alkynes). Through these reactions, it was demonstrated that an acidic co-catalyst can increase the catalyst turnover significantly, enabling practical reaction rates at competitive catalyst loadings (<1mol%). Further investigation is currently underway to improve the understanding of the subtle principles underlying these experimental observations.
- 出版日期2016-11
- 单位东华大学
