摘要
This paper is devoted to the study of the nitridation of unreconstructed and reconstructed (ae31 xae31)R +/- 9A degrees (0001) sapphire surfaces in an ammonia flow by reflection high-energy electron diffraction (RHEED). The experimental results show that sapphire nitridation occurs on the unreconstructed (1 x 1) surface, which results in AlN phase formation on the substrate surface. However, if sapphire nitridation is preceded by high-temperature annealing (1150A degrees C) resulting in sapphire surface reconstruction with formation of the (ae31 xae31)R +/- 9A degrees surface, the crystalline AlN phase on the sapphire surface is not formed during surface exposure to an ammonia flow.
- 出版日期2015-7