Novel Br center dot center dot center dot pi(Chelate) Interaction in a 1D Coordination Polymer Revealing Aromaticity

作者：Dutta Basudeb; Pratik Saied Md; Jana Srikanta; Sinha Chittaranjan; Datta Ayan; Mir Mohammad Hedayetullah

来源：ChemistrySelect, 2018, 3(16): 4289-4291.

DOI：10.1002/slct.201800738

• Br???π(Chelate) Interaction
• Coordination Polymer
• Copper
• 16-Member Chelate Ring

Abstract(#br)A one‐dimensional coordination polymer (1D CP) [Cu(nip)(4‐brpy)2] (1) containing 16‐member metal‐ligand chelate ring exhibits unprecedented Br???π(chelate) interaction. The nucleus‐independent chemical shifts (NICS) calculation reveals that the chelate ring has aromaticity an...

• 出版日期2018-4-30