A neutral Pt-3 stack unsupported by any bridging ligand

作者：Holland Lars; Shen Wei Zheng; von Grebe Philipp; Miguel Pablo J Sanz; Pichierri Fabio^*; Springer Andreas; Schalley Christoph A; Lippert Bernhard

来源：Dalton Transactions, 2011, 40(19): 5159-5161.

DOI：10.1039/c0dt01408g

Pt center dot center dot center dot Pt center dot center dot center dot Pt interactions via their d(8) orbitals, combined with pi-pi stacking of deprotonated, chelating 2-(3'-pyrazolyl)pyridine (pyzpy) ligands, are responsible for transPt(pyzpy)(2) (2) crystallization in a stack of three molecules unsupported by any bridging ligand.

• 出版日期2011