An aromatic-antiaromatic switch in P-heteroles. A small change in delocalisation makes a big reactivity difference

作者:Nyulaszi L*; Holloczki O; Lescop C; Hissler M; Reau R
来源:Organic and Biomolecular Chemistry, 2006, 4(6): 996-998.
DOI:10.1039/b516836h

摘要

The low aromaticity of phosphole can be switched to low antiaromaticity by oxidizing the phosphorus atom. This subtle change in the mode of delocalisation alters substantially the chemical behaviour of these heteroles.

  • 出版日期2006