Microwave-Assisted Solvent-Free Diels-Alder Reaction - A Fast and Simple Route to Various 5,6-Substituted Norbornenes and Polychlorinated Norbornenes

作者：Dejmek Milan; Hrebabecky Hubert; Sala Michal; Dracinsky Martin; Nencka Radim^*

来源：Synthesis, 2011, (24): 4077-4083.

DOI：10.1055/s-0031-1289610

• Diels-Alder reactions
• bicyclic compounds
• cycloadditions
• norbornene
• microwave
• polychlorinated norbornanes

A series of 5,6-substituted norbornenes and 5,6-substituted polychlorinated norbornenes was prepared by using a microwave-assisted Diels-Alder reaction. This procedure proved very versatile, fast, and with an easy workup step, and therefore suitable even for large-scale synthesis.

• 出版日期2011-12