A DFT and QTAIM study of the novel d-block metal complexes with tetraoxa[8]circulene-based ligands

作者:Karaush Nataliya N; Baryshnikov Gleb V; Minaeva Valentina A; Minaev Boris F
来源:New Journal of Chemistry, 2015, 39(10): 7815-7821.
DOI:10.1039/c5nj01255d

摘要

The transition metal complexes with the tetraoxa[8]circulene-based ligand are designed. The complexation process strictly depends on matching of the d-metal cation size to the size of the tetraoxa[8]circulene formed cavity.

  • 出版日期2015