A novel route to copper(II) detection using %26apos;click%26apos; chemistry-induced aggregation of gold nanoparticles

作者:Hua Carol; Zhang William H; De Almeida Swahnnya R M; Ciampi Simone; Gloria Danmar; Liu Guozhen; Harper Jason B; Gooding J Justin*
来源:Analyst, 2012, 137(1): 82-86.
DOI:10.1039/c1an15693d

摘要

A simple colorimetric method for the detection of copper ions in water is described. This method is based on the %26apos;click%26apos; copper(I)-catalyzed azide-alkyne cycloaddition reaction and its use in promoting the aggregation of azide-tagged gold nanoparticles by a dialkyne cross-linker is described. Nanoparticle cross-linking, evidenced as a colour change, is used for the detection of copper ions. The lowest detected concentration by the naked eye was 1.8 mu M, with the response linear with log(concentration) between 1.8-200 mu M. The selectivity relative to other potentially interfering ions was evaluated.

  • 出版日期2012