A novel two-dimensional network self-assembled by the narrowest ladder cations [Cu(CH3COO)(bpe)(H2O)](n+)(n) containing the Cu-2(mu-O)(2) cores and the dimeric anions [Cu-2(nta)(2)(bpe)](2-) through hydrogen-bonding interaction

作者：Li BL^*; Li BZ; Lang JP; Zhang Y

来源：Inorganic Chemistry Communications, 2003, 6(6): 725-727.

DOI：10.1016/S1387-7003(03)00093-5

• ladder
• crystal structure
• two-dimensional network
• hydrogen-bonding

A novel complex [Cu(CH3COO)(bpe)(H2O)](n) . n/2[Cu-2(nta)(2)(bpe)].6nH(2)O) (bpe = trans-1,2-bis(4-pyridyl)ethylene) was synthesized and characterized. The molecule structure shows that it is composed of the ladder-like double chain cations [Cu(CH3COO)(bpe)(H2O)](n)(n+) and the dimeric anions [Cu-2(nta)(2)(bpe)](2-). Through bridging oxygen atom of the acetate, the Cu-2 (mu-O)(2) core is formed. The ladder-like chain cation is the narrowest ladder [3.422(3) Angstrom]. Two-dimensional undulating network is constructed by the cations and the dimeric anions through hydrogen-bonding interactions.

• 出版日期2003-6
• 单位苏州大学; 宿州学院