Development of Thermophysical Property Measurement for Liquid Fe Using Noncontact Laser Modulation Calorimetry

作者：Sugie Kazutoshi^*; Kobatake Hidekazu; Fukuyama Hiroyuki; Baba Yuya; Sugioka Ken ichi; Tsukada Takao

来源：Journal of the Iron and Steel Institute of Japan, 2010, 96(12): 673-682.

DOI：10.2355/tetsutohagane.96.673

• thermophysical property
• heat capacity
• thermal conductivity
• liquid iron
• electromagnetic levitation
• laser calorimetry

Newly developed noncontact modulation laser calorimetry has enabled us to measure accurate thermophysical properties such as thermal conductivity and heat capacity of high temperature liquid metals with suppressing chemical reactions and convections. However, in spite of the demand for accurate thermophysical properties as input parameters in precise numerical simulation for casting and welding processes, it is still difficult to measure those of liquid iron (Fe). The difficulty is caused by the high density and electrical resistivity of liquid Fe. In this study we designed a new levitation coil having high lifting force with moderate heating for liquid Fe. Furthermore, a superconducting magnet, which has a maximum de magnetic field of 10 T, was equipped to the measurement system to suppress the convection in the liquid Fe. The isobaric molar heat capacity of liquid Fe was successfully measured at lower dc magnetic field (3 and 4 T). This can be explained by the accomplishment of the semi-adiabatic condition caused by the higher thermal conductance of the convection. The isobaric molar heat capacity of liquid Fe was determined as follows; c(p)=45.5 +/- 4.1 J center dot mol(-1)center dot K(-1) [1816-1992K]. On the other hand, the apparent thermal conductivity of liquid Fe decreased with increasing dc magnetic field, and then finally converged to be 38.7 +/- 2.5 W center dot m(-1)center dot K(-1) [1794-2050 K] above 9 T due to the suppression of convection.

• 出版日期2010-12