A novel open-framework zinc phosphite, Zn-3(HPO3)(4)-Ni(en)(2)(H2O)(2), templated by a transition-metal complex

作者：Lin, ZE; Zhang, M; Zheng, ST; Yang, GY^*

来源：European Journal of Inorganic Chemistry, 2004, (5): 953-955.

DOI：10.1002/ejic.200300601

• open framework
• inorganic solid
• zinc
• nickel
• template synthesis

A new three-dimensional zinc phosphite, Zn-3(HPO3)(4)- Ni(en)(2)(H2O)(2), which is the first example of an open-framework metal phosphite templated by a transition-metal complex, was hydrothermally synthesized. The connectivity of the strictly alternating ZnO4 and HPO3 units results in a three-dimensional framework with intersecting 8-ring and 12-ring channels, in which the transition-metal complexes reside.

• 单位
  中国科学院福建物质结构研究所; 结构化学国家重点实验室